Photochemical Machining Chemical Milling Precision Metal

Photochemical Machining & Acid Metal Etching Vector Phototool Prepress Guide

Published by SpotItLive Technical Prepress Team • Engineering Reference

Photochemical Machining (PCM)—also referred to as chemical milling, photo-etching, or photochemical etching—is an ultra-precision subtractive manufacturing process used to produce burr-free, stress-free micro-metal components. Common products include lead frames, RF/EMI shielding cans, medical implant meshes, speaker grilles, spring contacts, optical encoder discs, and luxury decorative metal inlays.

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Unlike mechanical stamping or laser cutting, PCM uses chemical etchants (primarily aqueous Ferric Chloride, $FeCl_3$) to dissolve unmasked metal areas. Because the acid spray dissolves metal laterally underneath the photoresist as well as vertically through the sheet, prepress tooling engineers must mathematically compensate the vector artwork to ensure target dimensional tolerances.

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1. The Geometry of Acid Undercut and Etch Factor ($EF$)

As acid attacks exposed metal, it bites into the sidewall beneath the polymerized photoresist mask. This lateral erosion is termed undercut ($U$). The ratio of downward vertical etching depth ($d$) to lateral undercut ($U$) is defined as the Etch Factor ($EF$):

EF = Vertical Etch Depth (d) / Lateral Undercut (U)
U = d / EF

In standard double-sided etching (where acid is sprayed simultaneously onto both the top and bottom faces of the metal sheet):

Prepress Compensation Rule:
  • Holes & Slots (Apertures): Acid makes holes bigger. Therefore, the vector phototool aperture must be narrowed (shrunk) by 2 * U.
  • Metal Lands & Lead Fingers: Acid erodes both sides of metal lines. Therefore, the vector phototool land must be broadened (expanded) by 2 * U.

2. Double-Sided "Hourglass" Cross-Section Profile

In double-sided spray etching, the two chemical etching fronts meet at the sheet midpoint. This creates an hourglass cross-section with a knife-edge waist at the center of the sheet:

3. Half-Etching for Bend Lines and Relief Pockets

One of PCM's most powerful capabilities is half-etching (blind etching). By exposing a feature on only one side of the dual-sided phototool while keeping the opposing side solid black/opaque, the acid dissolves 50% to 60% of the metal thickness:

4. Alloy Etch Factors and Tolerances

Alloy Group Standard Chemistry Double-Sided EF Standard Tolerance (±) Typical Applications
Austenitic Stainless (301, 304, 316) Ferric Chloride ($FeCl_3$) 1.8 - 2.2 : 1 ± 10% Thickness Medical filters, springs, shims, encoder discs
Copper & Brass (C110, C260) Cupric Chloride / Ferric 2.2 - 2.8 : 1 ± 8% Thickness Lead frames, RF shields, heat sinks, busbars
Beryllium Copper (C17200) Ferric Chloride 2.0 - 2.4 : 1 ± 10% Thickness EMI gaskets, high-cycle electrical contacts
Nickel Alloys (Inconel, Monel) Acidified $FeCl_3$ 1.4 - 1.8 : 1 ± 12% Thickness Aerospace fuel filters, chemical seals
Aluminum (5052, 6061) Alkaline / Acid mix 1.2 - 1.6 : 1 ± 15% Thickness Lightweight electronics housings, aerospace shims

5. Phototool CAD & Vector Requirements

Laser photoplotters print film emulsions at resolutions exceeding 25,000 to 40,000 DPI. To achieve dimensional accuracy down to ±5 microns, vector source files must adhere to strict prepress standards:

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